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Beilstein J. Org. Chem. 2016, 12, 950–956, doi:10.3762/bjoc.12.93
Graphical Abstract
Scheme 1: Transformations of 3-aryl-N-(aryl)propiolamides 1 into 4-arylquinolin-2(1H)-ones 3 or 4,4-diaryl-3,...
Figure 1: Molecular structure of 2f (ellipsoid contours of probability levels are 50%).
Scheme 2: N-Formylation and N-acylation of dihydroquinolinones 2.
Scheme 3: Superelectrophilic activation of the N-formyl group of compounds 5 and their reaction with benzene.
Figure 2: LUMO of species C1 and D1.